OresOre DepositsGold  AuOre mineralsEconomic GeologyOre deposit environmentsSlide 7Geochemical TrapsHydrothermal Ore DepositsMassive sulfide depositsVermont CopperbeltMinerals associated with economically recoverable metalsSulfides Part 1Sulfide MineralsIron SulfidesOther important sulfidesSulfides are reduced minerals  what happens when they contact O2?Actively Oxidizing PyriteAMD neutralizationSlide 20Slide 21Slide 22Ores•Principally we discuss ores as sources of metals•However, there are many other resources bound in minerals which we find useful•How many can we think of?Ore Deposits•A deposit contains an unusually high concentration of particular element(s)•This means the element(s) have been concentrated in a particular area due to some process•What sort of processes might concentrate these elements in one place?Gold  Au•Distribution of Au in the crust = 3.1 ppb by weight  3.1 units gold / 1,000,000,000 units of total crust = 0.00000031% Au•Concentration of Au needed to be economically viable as a deposit = few g/t  3 g / 1000kg = 3g/ 1,000,000 g = 0.00031% Au•Need to concentrate Au at least 1000-fold to be a viable deposit•Rare mines can be up to a few percent gold (extremely high grade)!Ore minerals•Minerals with economic value are ore minerals•Minerals often associated with ore minerals but which do not have economic value are gangue minerals•Key to economic deposits are geochemical traps  metals are transported and precipitated in a very concentrated fashion–Gold is almost 1,000,000 times less abundant than is ironEconomic Geology•Understanding of how metalliferous minerals become concentrated key to ore deposits…•Getting them out at a profit determines where/when they come outOre deposit environments•Magmatic–Cumulate deposits – fractional crystallization processes can concentrate metals (Cr, Fe, Pt)–Pegmatites – late staged crystallization forms pegmatites and many residual elements are concentrated (Li, Ce, Be, Sn, and U)•Hydrothermal–Magmatic fluid - directly associated with magma–Porphyries - Hot water heated by pluton–Skarn – hot water associated with contact metamorphisms–Exhalatives – hot water flowing to surface–Epigenetic – hot water not directly associated with pluton•Sedimentary–Placer – weathering of primary minerals and transport by streams (Gold, diamonds, other)–Banded Iron Formations – 90%+ of world’s iron tied up in these–Evaporite deposits – minerals like gypsum, halite deposited this way–Laterites – leaching of rock leaves residual materials behind (Al, Ni, Fe)–Supergene – reworking of primary ore deposits remobilizes metals (often over short distances)Ore deposit environmentsGeochemical Traps•Similar to chemical sedimentary rocks – must leach material into fluid, transport and deposit ions as minerals…•pH, redox, T changes and mixing of different fluids results in ore mineralization•Cause metals to go from soluble to insoluble•Sulfides (reduced form of S) strongly binds metals  many important metal ore minerals are sulfides!•Oxides – Oxidizing environments form (hydroxy)oxide minerals, very insoluble metal concentrations (especially Fe, Mn, Al)Hydrothermal Ore Deposits•Thermal gradients induce convection of water – leaching, redox rxns, and cooling create economic mineralizationMassive sulfide deposits•Hot, briny, water leaches metals from basaltic ocean rocks•Comes in contact with cool ocean water•Sulfides precipitate Vermont Copperbelt•Besshi-type massive sulfide deposits•Key Units:–Giles Mountain formation – More siliciclastic, including graphitic pelite, quartoze granofels (metamorphosed greywacke), hornblende schist, amphibolite–Standing Pond Volcanics – mostly a fine grained hormblende-plagioclase amphibolite, likely formed from extrusive basaltic rocks (local evidence of pillow structures in St. Johnsbury). Felsic dike near Springfiled VT yielded a U-Pb age of 423± 4 Ma.–Waits River formation – Calcareous pelite (metamorphosed mudstone), metalimestone, metadolostone, quartzite.Minerals associated with economically recoverable metals•Elemental forms•Sulfides•Oxides•Carbonates•Sulfate saltElemental copperChalcocite, Cu2S Chalcanthite, CuSO4*5H2OMalachite, Cu2CO3(OH)2Cuprite, Cu2OSulfides Part 1•Substitution into sulfides is very common•As and Se substitute for S very easily•Au can substitute in cation sites (auriferrous minerals)•Different metals swap in and out pretty easily  Cu and Fe for instance have a wide range of solid solution materialsSulfide Minerals•Minerals with S- or S2- (monosulfides) or S22- (disulfides) as anionic group•Transition metals bonded with sulfide anion groupsIron Sulfides•Mackinawite – FeS•Greigite – FexSy •Pyrite – FeS2 (cubic)•Marcasite – FeS2 (orthorhombic)•Troilite – FeS end member•Pyrrhotite – Fe1-xS (slightly deficient in iron)•Arsenopyrite – FeAsS•Chalcopyrite – CuFeS2Other important sulfides•Galena – PbS•Sphalerite/wurtzite – ZnS•Cinnabar – HgS•Molybdenite – MoS•Covellite – CuS•Chalcocite – Cu2S•Acanthite or Argenite – AgS•Stibnite – Sb2S3•Orpiment – As2S3 ; Realgar – AsSSulfides are reduced minerals  what happens when they contact O2?•This is the basis for supergene enrichment and acidic mine drainageActively Oxidizing Pyrite•FeS2 + 3.5 O2 + H2O  Fe2+ + 2 SO42- + 2 H+•FeS2 + 14 Fe3+ + 8 H2O  15 Fe2+ + 2 SO42- + 16 H+•14Fe2+ + 3.5 O2 + 14H+  14 Fe3+ + 7 H2O•Sulfur species and H+ generation:–FeS2 + 2 Fe3+ 3 Fe2+ + ¼ S8 + 0 H+–FeS2 + 7 Fe3+ + 3 H2O 8 Fe2+ + 0.5 S4O62- + 6 H+AMD neutralization•Metals are soluble in low pH solutions – can get 100’s of grams of metal into a liter of very acidic solution•HOWEVER – eventually that solution will get neutralized (reaction with other rocks, CO2 in the atmosphere, etc.) and the metals are not so soluble  but oxidized S (sulfate, SO42-) is very soluble•A different kind of mineral is formed!Ely