CHEM 334: Final Exam
31 Cards in this Set
| Front | Back |
|---|---|
|
H2SO4 + R
|
ester
|
|
CH2N2
|
replaces -OH w/ -OMe
|
|
SOCl2
|
adds a Cl
|
|
heat
|
too hot for HOOC so it leaves
|
|
H2O/base
|
replace halogen w/ -OH
|
|
H2O
|
forms 2 HOOCR's
|
|
NaOH/H2O and heat
|
replace N-H group w/ O-
|
|
H3O+
|
makes double bond of 2,3 C w/o dropping -OH
|
|
H+/H2O and heat
|
break open cyclo, add -OH and -NH2
|
|
H+
|
reduces carbonyl to -OH
|
|
H2N-CH3
|
NH-CH3 replaces leaving group
|
|
NH3
|
ester leaves and NH2 replaces it
|
|
pyridine
|
forms an anhydride
|
|
R-MgBr
|
replaces LG with R group, forms -OH
|
|
(CH3)2 CULi
|
replaces LG w/ R group
|
|
LiAlH4/H2O
|
forms an NH2 or removes carbonyl
|
|
P4P10/heat
|
makes nitrile
|
|
acid anhydride/heat
|
makes nitrile
|
|
-OH
|
makes an O- on the carbonyl
|
|
X2/acid or base
|
adds "X" to the alpha carbon
|
|
Br2/OH-
|
forms an O- on empty carbon
|
|
LDA (strong base)
|
O becomes -, drops double bond to next carbon
|
|
NH2CH3
|
adds NCH3 to where R was
|
|
NaOH/R/H2O
|
R adds to alpha carbon
|
|
X-R/H3O+
|
R group leaves, attaches to ring, adds carbonyl group
|
|
KMnO4
|
carboxylic acid
|
|
DiBAL-H, -78/H2O
|
breaks open cyclo and adds -OH/ turns a nitrile into an aldehyde
|
|
NH2NH2/KOH
|
removes carbonyl group
|
|
(Ph)3P-CH2
|
removes O from carbonyl
|
|
HNO3/H2SO4
|
adds -NO2
|
|
LiAlH(OtBu)3, -78/H2O
|
remove -X and replace with H
|
CHEM 334: Final Exam