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atoms, isotopes, molecules
· Atomic number- number of protons in nucleus · Mass number- number of protons and neutrons in a nucleus · Isotope: atoms with the same atomic number by different number of neutrons
covalent, ionic bonds
· Ionic bonding some atoms loose electron from outer shell and other atoms gain electrons in outer shell · Covalent bonding: electrons in outer shell of atoms are shared
Structure of the polar water molecule, the hydrogen bond
· Water is a polar covalent molecule · Is formed by 2 hydrogen joining together with oxygen in a shared covalent bond · Hydrogen bonding: Because of polar molecules they want to line up like magnets, extra bond is the hydrogen bond · Hydrogen bonding causes su…
Properties of water
· high latent heat capacity (weather modification)
 · freezing and boiling temperatures (liquid water at earths surface) · 
expansion upon freezing
-high surface tension (capillarity)
 · high dielectric constant (dissolving power)
Changes of state in water: latent heats of melting and vaporization
· 1 calorie- is the amount of heat required to raise the temperature of 1 gram of pure water by 1 degree Celsius · latent heat of melting- the heat energy that must be added to 1 g of a substance at its melting point convert to a liquid 80 cal/g C degrees · latent hea…
heat capacity of land vs. water
· heat capacity is the amount of heat energy required to raise the temperature of a substance by 1 degree centigrade · high heat capacity can absorb large quantities of heat with only a small change in temp · pure water has high specific heat = 1 c per g bc it takes m…
as temp increases...
· Unbonded molecules pack more closely together density increases · Greater proportion of H-bonded ice-like clusters density decreases
Solution and dissolving power of water
· dissolved solids reduce the freezing point of water · water is the solvent for the solution that is ocean water · salts are the solutes in the ocean water · salinity is the amount of dissolved solids in seawater · Parts per thousand (g/kg) or (‰)- gr…
salts in seawater, def and measurement of salinity
chloride, sodium, sulfate, magnesium, calcium, potassium all dissolved in water · what determines salinity? – tastes, optical refractometer, titration for Cl ion, electrical conductivity · highest salinity- atlantic ocean closer to equator · salinometer- measures e…
Density of pure water and seawater: dependence on T,S
· sea ice forming and evaporation increase salinity · Pure water has a maximum density of 1.000 g/cm3 at 4°C · Ice floats because its density is 0.9170 g/cm3 · At T=20 °C, S=35 ppt, seawater density = 1.0247 · Increased salinity, increased density ·…
Acidity, buffering, PH
· Acidity- is a measure of reactivity of a solution associated with its hydrogen ion concentration · Alkalinity- is a measure of the buffering capacity of a solution (ability to NEUTRALIZE the hydrogen bond) · the pH of the solution tells you its degree of acidity of …
Energy from the sun
·solar flairs- huge amounts of energy (earth is tiny compared to it)
Seasons and Earths orbit
· the tilt of the earths axis relative to the ecliptic caused seasons – always points towards the north star · coldest day is the winter equinox- directly above tropic of Capricorn · longest day is the vertical equinox – directly above equator · heat is gained…
global heat budget and redistribution of heat
· sun strikes low latitiudes at a high angle so the raditons is concentrated in a relatively small area · earths atmosphere absorbs some radiation, less strikes the high latitude · energy of sun covers more surface area
-greater thickness of atmosphere (beam of light …
coriolis effect on air and water circulation
· the coriolis effect- go in a tangent direction of the way the merry go round is turning if you let go · northern hemisphere follow curved paths to the right/ south, left · effect greates at the poles, and 0 at the equator · depends on your latitude, speed of…
atmospheric circulation: hadley, ferrell and polar cells
· Northeast trades blow from the NE to SE · In the ocean the winds are opposite · In the ocean the north current flows towards the north · Polar cell- are at the pole, polar easteries · Ferrell cell- are at ground level and come from W. Hadley cell (NE…
water and cold fronts: airflow around low and high pressure centers
· Clockwise (anticyclonic) winds around high pressure cells · Counterclockwise (cyclonic) winds around low pressure cells · Air or water flow around a low-pressure center in the Northern Hemisphere
hurricanes, cyclones and typhoons: energy source, circulation, storm surges
· Anticyclonic is clockwise winds around high pressure cells · Cyclonc is counterclockwise winds around low pressure cells · Cycogenesis a wave distribution of the polar front (what produces mid latitude weather) · Tropical cyclones (hurricanes)- huge rotating…
greenhouse effect
· Greenhouse gasses absorb energy radiated by the earth back into the atmosphere, change of wavelength is the key · Keeps the earth at 15 degree C · Without the effected it would be -18 · The amount of greenhouse gasses that come have to equal the amount going…
sunlight penetration into the ocean
· Wavelength of max radition is inversely proportional to the temperature · Sun is 600 and earth 18 degrees C · Energy that is reflected from the surface back to space is albedo
direct and indirect measurements of atmospheric CO2
· Carbon dioxide has an increased -(400 x10^3) concentration (ppbv) 
-.5 rate of increase (% per year)
-60 relative contribution (%) · Methane has an increased -1.7x10^+3 concentration (ppbv)
-1 rate of increase (% per year)
-15 relative contribution (%)
Impacts of climate change: weather mods, melting glaciers, sea level rise, acidification
· Human activites are causing carbon dioxide and other greenhouse gases to accelerate · Recent record shows increase in greenhouse gases since industrial revolution · Over 140 years 1 degree of C increase
human induced changed in the atmosphere
· Potential natural causes of climate change: -changes in solar energy flux
-variations on earth's orbit
-volcanic eruptions
-tectonic movements of crustal plates · Consequences of greenhouse: -shifts in weather patterns (warm water oceans)
-global rise in sea level (melting …
sensitivity of the arctic to climate change
· Caused a permanent ice cover on the sea surface from low pressures · Ice forms
Wind- driven ocean circulation
· Horizontal currents that are caused by winds blowing over the surface · Thermohlaine currents: vertical currents caused by sinking of high density waters and rising of low density waters
Subtropical gyres and western boundary currents
· Atlantic ocean surface circulation: north gyre o Goes clockwise, driven by westies · Atlantic ocean surface circulation: south gyre o Counterclockwise, driven by trade winds · Suptropical gyres: -equatorial current
-western boundary currents (west side of oc…
special significance of the Antarctic cicumpolar current
....
ekman spiral, ekman transport, geostrophic currents
· V walfrid Ekman developed a circulation model called the Ekman layer · The layer flows at 45 degrees to the winds and is confide to the top 100 m, net flow is 90 degrees to the wind (Ekman transport) · The transport is 90 degrees to the right in the NH and 90 to the…
Coastal and equatorial upwelling: biological significance
· Costal Upwelling is caused by ekman transport pulling near-surface waters away from the coast · Deeper waters "upwell" (move upward" to replace the surface waters moved offshore · the deep waters usually are cold and rich in nutrients and dissolved oxygen · …
Convergence and divergence zones in the ocean
...
atlantic ocean surface currents, the loop current and the gulf stream
· large tropical gyres in each hemisphere, driven by Trades and Westerlies · warm water moves poleward in western boundary current · atlantic ocean surface currents: cooler water moves towards equators on the east sides · atlantic ocean surface currents: south…
Pacific and Indian ocean circulation compared to atlantic
· Antarctic circumpolar current is the only current that can completely circle the earth · Loop current eddy usually breaks off and creates stong clockwise currents · Gulf stream connects with florida current · Warm currents can come in between cold water mend…
el nino/la nina
· El Nino influx of WARM water occurring every 5-10 years · the onset of El Nino is associated with the weakening of the Trade Winds in the Pacific Ocean · temperature difference is called anomaly · La Nina influx of COLD water · La nina can cause drou…
thermohaline circulation and deep water formation
· thermohaline circulation is the vertical movement of ocean water driven by density differences that result from combined effects of temp and saline
atlantic water masses and the layer cake vertical structure
· stable stratification (science experiment) resist vertical mixing · unstable stratification (science experiment) easily mixed
-convection/overturning occurs · 3 layer cake (with frosting) contains: warm surface layer (frosting)
-Antarctic Intermediate Water (AAIW)
-…
deep circulation patterns connecting major oceans
· Indian Ocean creates circulation called monsoons · Monsoon NH winter-air is cold, atmospheric high pressure over the content and moves Southwest · Monsson NH summer-low pressure (hot land)- go from southwest and goes to the right · pacific is 3 times wider t…
exploration and circulation of the arctic ocean
· Antarctic Circumpolar Current or West Wind Draft is the only current that flows completely around the globe from West to East · Antarctic Divergence separates the East and West Wind Drift currents and is an upwelling region · does the pacify extend as long as the at…

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