Chemistry 14BL Pre lab Report Guidelines for the Kinetics Experiment The Experimental Procedures for this Experiment are Provided as a Handout I On line Technique Videos For This Experiment Click on the title below to download the video require Real Player 1 Laboratory Safety this video was shown on the first day of the lab 2 Solution Preparation 3 Spectrophotometric Analysis If you have trouble downloading the videos go to the following Web site and click on the appropriate title to download the video http oid ucla edu Webcast Chemistry On line resources and tutorials for chemical kinetics II Pre Lab Report Guideline IMPORTANT Make sure that you follow the proper laboratory safety protocol refer to the course syllabus BEFORE going to the lab A laboratory safety check will be conducted at the beginning of the lab You will be dismissed from the laboratory if you do not have the proper safety protocol Please also make sure that you show up to the lab on time Any pre lab reports that are NOT turned in within the first ten minutes of the lab section will not be accepted for grading The title of the experiment A reference identifying the procedure handout A short introduction summarizing the goals of the experiment AND the techniques that you will use in the experiment A brief flow chart summary of the procedures of the experiment Calculate the approximate molarity for solution 3 and the sodium hyprochlorite assume 6 15 by weight to volume You will need to read the lab procedure in order to complete these calculations SHOW ALL YOUR WORK Chemistry 14BL Pre lab Report Guidelines for the Kinetics Experiment The Experimental Procedures for this Experiment are Provided as a Handout II Pre Lab Report Guideline MSDS information for sodium hypochlorite concentration between 5 6 by weight and volume and FD C RED 3 Erythrosine B Note For FD C Red 3 MSDS go to the following website and type Erythrosine B in the search engine http chemfinder cambridgesoft com Note In MSDS select the site that gives you the MSDS information closest to the concentration or grade listed above for each individual chemical You should record the following MSDS information in your notebook for the chemicals listed above Printouts directly from Web pages will NOT be accepted for grading Important Reference the site i e write down the URL address that you used for each of the chemical a b c d e f Product Name Chemical Formula Formula Weight Melting Point Boiling Point and Density Health Hazard Data summarize in your own words Spill and Disposal procedures summarize in your own words Note Not all information is available for this particular compound Make sure you check all the links in the CS Chemfinder Web site If a particular information could not be found cite the URL address of the link s that you used to search for that particular information Use NEW pages in the lab notebook for the following items A BLANK table to record the preliminary information on the weight of the dye bleach concentration and initial solution absorbances Set up a BLANK data table to record the measured absorbances and times for EACH of the reaction trial Leave space for a heading that will identify the trial number and the experimental conditions for the trial during the lab period Chemistry 14BL Post lab Report Guidelines for the Kinetics Experiment This is a GROUP Report I DATA DATA ANALYSIS MUST show ALL your work in order to receive any credit Write down the names of all the members in the group Write out the responsibility of each member both for the experiment and for the post lab report Calculate the molarity for the bleach solution you may assume that the stock bleach solution contains only NaOCl and that the concentration given on the bottle has a unit of w v Note Make sure that you are using the w v given on the BOTTLE of NaOCl in the lab for the above calculation Calculate the precise molarity of food dye solution 1 food dye solution 2 food dye solution 3 Calculate the initial concentration molarity of the food dye solution in EACH trial Using the Beer s law formula calculate the molar extinction coefficient for the food dye You may assume that the diameter of the culture tube to be 1 00cm Hint for this part use the absorbance you obtained in the lab under Calibration of Spectrophotometer to find the molar extinction coefficient of the red food dye In tabular form now set up an EXCEL spreadsheet table for EACH trial Label the columns as time absorbance dye ln dye and 1 dye Print out the data and attach them to your report Note means the concentration has a unit of mol L Hint From Beer s law use your experimental absorbances measured at various times together with the molar extinction coefficient of the dye to calculate the dye at various time for EACH TRIAL Provides a legend for each table that gives the experimental condition temperature volumes of each reagent etc Chemistry 14BL Post lab Report Guidelines for the Kinetics Experiment This is a GROUP Report II Graphs Using EXCEL plot the following three graphs for EACH TRIAL dye vs time ln dye vs time 1 dye vs time Be sure to title your graphs and label the axes including units EACH of your graph MUST include a legend for the experimental condition of EACH TRIAL Print EACH graph on a separate piece of paper III Analysis From a visual inspection of the plots see above select the linear relationships to establish a the order of the reaction with respect to the dye You should do this for each of your trial Note if you have trouble determining the order with respect to dye for trial 5 6 based on visual inspection try using trial 3 4 as your reference Refer to lecture guide for the relationship between the shape of the graph and the order of the chemical species By comparing the ratio of the slopes of the lines for trials 1 5 determine b the order of the reaction with respect to hypochlorite Refer to the lab handouts page 2 3 on how to find the order of the hypochlorite using the ratio of the slopes By comparing the ratio of the slopes of the lines for trials 1 6 determine b the order of the reaction with respect to hypochlorite Compare the two values of the b Do they agree Using the plots that give linear relationships determine the rate constant k for each trial Do they agree with each other The rate constants should have the appropriate units b Hint Slope k NaOCl where b is the order of the bleach you found earlier NaOCl is the INITIAL MOLARITY of the sodium hyprochlorite for the
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