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If delta G is positive, the reaction is...
non spontaneous (endergonic) and energy must be consumed,
If delta G is negative, the reaction is...
spontaneous (exergonic) and energy is released
anabolic pathways
Couple the synthesis of energy Hydrolysis of ATP Energy requiring Muscle contraction, transport, and synthesis of cellular compounds, photosynthesis
Anabolic/Catabolic
Anabolic: energy requiring gluconeogenesis, glycogenisis Catabolic: releases energy glycolysis, glycogenolysis
L/D isomer
OH on left of the carbon (L) OH on the right (D)
oxidized/ reduced
usually double bonded to Oxygen has more H+ after
ATP hydrolysis ATP+ H2O -->
ADP+Pi+7.31 kcal
AMP ADP ATP
1 phosphate 2 phosphate 3 phosphate
pI
The pH of a molecule at which it contains no net electric charge; isoelectric point.
Glycosidic bond
A covalent bond (-C-O-C-) that links two monosaccharides (sugars) together.
fermentation
from NADH/H+ --> NAD+
CAC results
12 ATP total (9 NADH, 3 FADH2) 3 NADH (step 3,4,8) 1 GTP (step 5) 1 FADH2 (step 6) releases 2 CO2 (step 3,4)
Acetyl-S-CoA is a reactant in which metabolic pathway or reaction?
Citric Acid Cycle
Acetyl-S-CoA is a product of which metabolic pathway?
Pyruvate dehydrogenase reaction
How many molecules of CO2 are produced from the complete oxidation of one acetyl-S-CoA?
2
anaerobic conditions
pyruvate is reduced to lactate increase the NAD+
aerobic (oxygen-rich) conditions
pyruvate is converted to acetyl-SCoA by the pyruvate dehyrogenase complex in the mitochondria
fermentation
pyruvate is decarboxylated to acetaldehyde
Glucose Metabolism and Energy Production
Insulin released when blood glucose concentration rises, stimulates glycogenesis Glucagon is released when blood glucose conc. drops Glycogenolysis breaks down glycogen to glucose
during starvation
Insulin falls, glucagon rises Liver mobilizes glycogen Glucose can be synthesized from non carbohydrate sources through gluconeogensis. Cori cycle provides pyruvate for the liver from lactate
How many ATP must be invested in the early reactions of glycolysis?
2
glycolysis
(anaerobic) The pathway in which a cell breaks down glucose into energy.
net equation of Glycolysis
production of 2 pyruvate molecules, 2 ATPs, and 2 NADH/H+s.

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