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Na2Fe(CO)4BrOBrONCuNOH2OH2+BF4–Zr(OPh)2Zr(OPh)2IHDPd(PPh3)4DHNNONiONN OCuOCu(I)Cu(II), Ni(II)Zr(IV)Zr(II)PdIHDHDPdII-Pd-D1. Propose a synthesis from bromobenzene and any materials with 4 carbons or less1) nBuBr2) PPh33)Pd(0), K3PO42. Indicate the formal oxidation state of the metals in each complex3. Predict the product. Explain with a detailed mechanismorPd(0)a possible solution not discussed in classoxidative additionalkene insertionsynsyn B-hydrideeliminationPd + HIOHOO–OMeLi MeLiO––OMeH3O+OHHOMeMeOCO2MeMeLiOCH3OLiH+MeODianion is stable until workup4 Ethyl benzoate is straightforward. For benzoic acid:LDAdoes not react with MeLiLDA enolizes the intermediate ketone. Thus, it cannot react further with


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UD CHEM 634 - PS 1 answers

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