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UT Knoxville CHEM 360 - chapter 21 aromatic map answer key

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Aromatic Reaction Map KeyYou should know the mechanisms of these, unless otherwise stated below.1. HNO3,H2SO42. Cl2, FeCl3(cat.)3. Br2, FeBr3(cat.)4. RCl, AlCl3(cat.) . Not on deactivated ring. Rearrangements5. RCOCl, AlCl3(full eqv.) Not on ring more deactivated than halo 6. SO3, H2SO47. H2O, H2SO48. KMnO4, H2SO4, Δ or CrO3, conc. H2SO4, Δ (not mechanism)9. X2, h10. KOH/EtOH (E2) 11. H2O (SN1 conditions)12. H2, Pd (not mechanism)And post Ch. 12 (no mechanisms, unless stated)13. CrO3,pyridine *if R’ = H)14. Clemmensen or Wolff-Kishner conditions15. Fe,HCl or H2,Pt or Sn/HCl16. NaNO2, HCl 17. H2O, HO- or Cu2O18. CuCl19. CuBr20. KI, H2O21. CuF22. CuCN23. Ar’H (activated ring)24. Mg, Et2O25. (1) ethylene oxide (2) H3O+27. H3PO228. any oxidizing agent, including O229. (1) CO2 (2) H3O+30. H2O31. H2O, H3O+,


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UT Knoxville CHEM 360 - chapter 21 aromatic map answer key

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