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UWL CHM 303 - Properties of Alkanes/Cycloalkanes

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CHM 303 1st Edition Lecture 7 Outline of Last Lecture Chapter 2: Alkanes and Cycloalkanes: Introduction to HydrocarbonsIII. Properties of Alkanes/Cycloalkanes A. Physical propertiesOutline of Current Lecture Chapter 2: Alkanes and Cycloalkanes: Introduction to HydrocarbonsIII. Properties of Alkanes/CycloalkanesB. Combustion Reactions IV. Oxidation-Reduction in Organic ChemistryA. OxidationB. ReductionChapter 3: Alkanes and Cycloalkanes: Conformations and cis-trans Stereoiso-mersI. Conformations of AlkanesCurrent LectureChapter 2: Alkanes and Cycloalkanes: Introduction to HydrocarbonsIII. Properties of Alkanes/CycloalkanesB. Combustion Reactions Ex. Reaction C6H14 structure H (kJ/mol) a. C6H14 + 19/2 O2 —> 6 CO2 + 7 H2O -4,163 b. C6H14 + 19/2 O2 —> 6 CO2 + 7 H2O -4,157These notes represent a detailed interpretation of the professor’s lecture. GradeBuddy is best used as a supplement to your own notes, not as a substitute.(b.) is more stable because it has a higher H value*Decrease in change of H = Decrease in stability*More branching (when comparing isomers) = More stability*IV. Oxidation-Reduction in Organic ChemistryA. Oxidation: adding bonds to oxygen and/or removing hydrogenB. Reduction: removing bonds to oxygen and/or adding hydrogenChapter 3: Alkanes and Cycloalkanes: Conformations and cis-trans Stereoiso-mersI. Conformations of AlkanesA. Eclipsed Conformation: when front and back are in alignmentB. Staggered Conformation: when front and back are not alignedEclipsed and Staggered are the two extremesC. Newman Projections: a form of drawing depicting one bond right be- hind anotherDe- picted below are Newman Projections of the Eclipsed Conformation with the back molecule shown just slightly off of the front molecule: they ARE in line, but this depiction is the best, and most accepted. The second in a Staggered Conformation, which is much more sta-ble than the Eclipsed.D. Torsion Angles1. Eclipsed: 0 degrees-each pair of eclipsing Hydrogens costs 4 kJ/mol2. Gouche: 60 degrees3. Anti: 180 degress (most


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UWL CHM 303 - Properties of Alkanes/Cycloalkanes

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