UMass Amherst CHEM 261 - Organic Chemistry Annotations 261 (4 pages)

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Organic Chemistry Annotations 261



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Organic Chemistry Annotations 261

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4
School:
University of Massachusetts Amherst
Course:
Chem 261 - Organic Chemistry

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Basic Hybridization Lewis Structures Sp1 or Sp have 2 total things attached atoms lone pairs Sp2 have 3 total things attached atoms lone pairs Sp3 have 4 total things attached atoms lone pairs Orbital diagrams To draw an orbital diagram find the hybridization of each atom Then draw the valence orbitals for each atom Valence orbitals Sp1 has 2 valence Sp orbitals Sp2 has 3 valence Sp2 orbitals Sp3 has 4 valence Sp3 orbitals Then determine which orbitals overlap to form bonds Sigma bonds happen with an s orbital overlaps a p orbital Pi bonds happen when a p orbital overlaps lengthwise side by side with another p orbital Single bonds are Always sigma bonds A double bond has one sigma and one pi bond A triple bond has one sigma and two pi bonds There is not automatically an s orbital on the middle atom The s orbitals will hang out at the end of each p orbital in a small overlap This is the orbital diagram for methane CH4 it is an Sp3 hybrid orbital it has 4 sigma bonds and no pi bonds Formal charge is easy it s just Formal charge of an atom number of valence electrons dots sticks Carbon on the periodic table is a valence number 4 Neutral Carbon has a neutral formal charge of 0 a cationic charge of 1 and an anionic charge of 1 Ionic 3 charge Nitrogen is a valence number 5 Neutral nitrogen has a formal charge of 0 a cationic formal charge of 1 and an anionic formal charge of 1 Ionic 3 charge Oxygen is valence number 6 a neutral formal charge of 0 a cationic formal charge of 1 and an anionic charge of 1 To find out how many lone pairs an atom has just rearrange the formula so that it says dots valence electrons formal charge sticks Resonance To Draw Resonance Structures memorize these rules Don t move single bonds Lewis structures describe single bonds correctly You only move lone pairs or double or triple bonds Make sure all resonance structures are valid Lewis structures Don t break the octet rule f or any of the resonance structures lone pairs sticks can t be above four



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