This course. Getting to know you/me/those who will help you and expectations.!! Handouts: 1) How I best learn.!!2) Some information and poster preference.!!3) Syllabus!!4) Schedule!!5) Project #1!!!Lecture 1 362 January 18, 2017!CHEM 362 Prof. Marcetta Darensbourg, Rm. 408. Phone # 845-5417 Descriptive Inorganic Chemistry Spring 2017 ² MWF 10:20 - 11:10 AM ² 255 Chemistry Website: http://www.chem.tamu.edu/rgroup/marcetta/ Office hours: Immediately following class on W or F, or by appointment TEACHING ASSISTANTS: ~~Xuemei Yang <[email protected]>; 418 Chemistry; Phone # 845-4837 Office hours: Tuesdays 4-5 pm. ~~Pokhraj Ghosh <[email protected]>; 420 Chemistry; Phone # 845-4837 Office hours: Fridays 5-6 pm. UNDERGRADUATE MENTORS: PEER LED TEAM LEARNING (PLTL) LEADERS ZACHARY MARTINEZ MAGY MAURICE MANUEL QUIROZ YICHENG TONG ADMINISTRATIVE ASSISTANT: (All Grade Records and special appointments) Abbey Kunkle [email protected]; 407 Chemistry; Phone # 845-5417 Office hours: Monday-Friday 8am-5pm WEBPAGE: http://www.chem.tamu.edu/rgroup/marcetta/chem362 TEXT: "Inorganic Chemistry", 6th Edition, Shriver & Atkins, W.H. Freeman and Company (ISBN-10: 1-4292-9906-1 | ISBN-13: 978-1-4292-9906-0)CHEM 362 Prof. Marcetta Darensbourg, Rm. 408. Phone # 845-5417 Descriptive Inorganic Chemistry Spring 2017 ² MWF 10:20 - 11:10 AM ² 255 Chemistry COURSE GRADING: SCHEDULE HOUR EXAM 1 15% FEBRUARY 15 HOUR EXAM 2 15% MARCH 29 HOUR EXAM 3 15% APRIL 19 FINAL EXAM 25% MAY 8 PROJECTS 15% QUIZZES: 15% POSTER DAY 1 APRIL 10 POSTER DAY 2 APRIL 12 Projects and the PLTL program: We are participating in the Peer Led Team Learning program. You will have available to you times when you can work on projects (especially the Posters) and also homework/review questions with a former 362 student as PLTL leader. You may choose your outside class time with one of the following: Manuel Quiroz, Zach Martinez, Magy Mekhail, Yicheng Tong. Their scheduled times are Monday –Sunday at 5 p.m. The day, the room, and student leader are to be announced. You are expected to select one leader within the team and stick with that team throughout the semester. The main project is the Poster, and each of these Leaders are expert in poster preparation. They will guide you through the process.By way of introducing the applications of Inorganic Chemistry, we will begin today’s lecture with two major topics from which the poster projects will be chosen and developed. .https://www.acs.org/content/acs/en/education/resources/highschool/chemmatters/past-issues/archive-2014-2015/smartphones.htmlMetals in Medicine Orvig, Science 300, May 9, 2003The Scope of Inorganic Chemistry Medicine'• MRI$• X-ray$contrast$imaging$• drugs$(arthri6s,$cancer,…$Biochemistry/Biology • metalloproteins • metalloenzymes • O2 binding • catalysis • ion transport Organic Chemistry • organometallics • metal compounds in synthesis/catalysis Materials Science • electrical and magnetic properties of solids • solid state structures • semiconductors • superconductors (high Tc) Geology/Geochemistry • synthesis and structure of minerals • stellar evolution • astrochemistry Organometallic Chemistry • new compounds • structures • catalysis INORGANIC CHEMISTRY • new compounds • geometrical and electronic structures • reactivityIf some universal catastrophe were to engulf the world, and humankind Could retain one scientific concept in order to rebuild civilization, what would that one concept be? Response for physicists (Richard Feynman in “Six Easy Pieces”): The modern idea of atoms. Response for chemists: The periodic table The periodic table encapsulates the concept of elements, organizes physical and chemical trends of substances, and compares the structure of the different atoms— All in a very small space. Inorganic Chemists think they own the Periodic Table. So, How did it all start?Well,. . . . https://www.youtube.com/watch?v=CMSYv_Z4SI8 Our whole universe was in a hot, dense state Then nearly fourteen billion years ago expansion started, wait The earth began to cool, the autotrophs began to drool Neanderthals developed tools We built a wall (we built the pyramids) Math, science, history, unraveling the mysteries That all started with the big bang! Hey! Since the dawn of man is really not that long As every galaxy was formed in less time than it takes to sing this song A fraction of a second and the elements were made The bipeds stood up straight, the dinosaurs all met their fate They tried to leap but they were late And they all died (they froze their asses off) The oceans and Pangea, see ya wouldn't wanna be ya Set in motion by the same big bang! It all started with the big bang!The first project: The Elements Stable vs.Unstable Isotopes Distribution of Stable Isotopes and Atomic Mass Detection by Mass Spectrometry84Be with t1/2 of ca. 10-18 sec 63Li + 21H 2 42He + EnergyStable vs. Unstable or Fissionable Nuclei Project no. 1. Nuclear Reactions; Web Elements; Mass SpectrometryWebElementsTM Periodic Table http://www.webelements.com Group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Period 1 1 H 2 He 2 3 Li 4 Be 5 B 6 C 7 N 8 O 9 F 10 Ne 3 11 Na 12 Mg 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar 4 19 K 20 Ca 21 Sc 22 Ti 23 V 24 Cr 25 Mn 26 Fe 27 Co 28 Ni 29 Cu 30 Zn 31 Ga 32 Ge 33 As 34 Se 35 Br 36 Kr 5 37 Rb 38 Sr 39 Y 40 Zr 41 Nb 42 Mo 43 Tc 44 Ru 45 Rh 46 Pd 47 Ag 48 Cd 49 In 50 Sn 51 Sb 52 Te 53 I 54 Xe 6 55 Cs 56 Ba *71 Lu 72 Hf 73 Ta 74 W 75 Re 76 Os 77 Ir 78 Pt 79 Au 80 Hg 81 Tl 82 Pb 83 Bi 84 Po 85 At 86 Rn 7 87 Fr 88 Ra **103 Lr 104 Rf 105 Db 106 Sg 107 Bh 108 Hs 109 Mt 110 Ds 111 Rg 112 Uub 113 Uut 114 Uuq 115 Uup 116 Uuh 117 Uus 118 Uuo *Lanthanoids *57 La 58 Ce 59 Pr 60 Nd 61 Pm 62 Sm 63 Eu 64 Gd 65 Tb 66 Dy 67 Ho 68 Er 69 Tm 70 Yb **Actinoids **89 Ac 90 Th 91 Pa 92 U 93 Np 94 Pu 95 Am 96 Cm 97 Bk 98 Cf 99 Es 100 Fm 101 Md 102 NoMass Spectra computer: http://www.sisweb.com/mstools/isotope.htmDimitri Mendeleev 1834-1907 ZE A Z = No. protons in nucleus, Atomic number A = Mass number; no. of protons + neutrons in nucleusCopyright © 2014 Pearson Education, Inc.Paradigm Shift: Development of Current Atomic Theory—Spectroscopy and Energy Levels in Atoms!!OR, !“Show me the