Chapter 15 Worksheet 01 Reactions Please provide the starting material reagents or product s Indicate stereochemistry where applicable 1 Br 1 CH3 3CO K 2 NBS hv 3 CH3O Na CH3OH 2 Show product and Mechanism HBr 0 oC HBr 40 oC www ochemweb com Major Product 3 H3O 0 oC Kinetic Product 4 At what temp is kinetic product favored Low or high HBr 1 eq Ans 5 Give the major product for the following reactions HBr 0 oC Br2 60 oC H3O 0 oC H3O 60 oC Br2 0 oC HBr 60 oC www ochemweb com 6 Give the major product for the following reactions HBr 0 oC Br2 0 oC H3O 0 oC H3O 60 oC Br2 60 oC HBr 60 oC www ochemweb com Major Product 7 Minor Product HBr 40 oC 8 9 Kinetic Product Thermodynamic Product Kinetic Product Thermodynamic Product HBr Br2 CCl4 www ochemweb com Major Product HBr 1 eq 10 0 C Major Product HBr 1 eq 11 40 oC HBr 1 eq 0 C 12 Major Product Major Product of 1 2 Addition 13 Br2 CCl4 At what temp is this product favored Low or high Ans www ochemweb com 14 Show product and Mechanism NBS 65 oC NBS 0 oC Light Light Major Product Minor Product NBS 0 oC 15 Light 16 NBS 65 oC Light Light 1 17 OH 18 NBS 0 oC 2 1 HBr 1 NBS Light 65 oC 2 CH3 3O K 2 NaSCH3 Light NBS 0 oC www ochemweb com