CPSC 382Organic Chem Ag Biol ProcTopic #5 - Oxygen-Containing Carbon Compounds1. Alcoholsa. definitionb. classificationc. nomenclatured. phenolse. properties of alcoholsf. alcohols and phenols as acids and basesg. reactions of alcoholsh. polyols2. Ethers and epoxidesa. definitionb. nomenclaturec. properties of ethersd. cyclic ethers and “crown ethers”3. Aldehydes and ketonesa. definitionb. nomenclaturec. common aldehydes and ketonesd. structure of the carbonyl groupe. reactions of the carbonyl groupf. formation of hemiacetals and acetalsg. tautomerism4. Carboxylic acidsa. definitionb. nomenclature1. monocarboxylic acids2. aromatic carboxylic acids3. dicarboxylic acidsc. physical properties of carboxylic acidsd. acidity of carboxylic acids5. Estersa. definitionb. nomenclaturec. esterificationd. saponification6. LactonesALCOHOLS:Classification: Nomenclature:H-bonding:Alcohols as acids: ETHERS AND EPOXIDES:Nomenclature:Epoxides: Properties: Cyclic Ethers:Crown Ethers:ALDEHYDES AND KETONES:Nomenclature:aldehydes:ketones: Structure of the Carbonyl Group:Nucleophilic Attack at the Carbonyl Group: Formation of Hemicacetals and Acetals:Keto/Enol Tautomerism: CARBOXYLIC ACIDS:Nomenclature:Aromatic Acids: Dicarboxylic Acids:Unsaturated dicarboxylic acids: Aromatic dicarboxylic acids: Properties of carboxylic acids:H-bonding in carboxylic acids: Acidity of carboxylic acids:ESTERS:Nomenclature:Esterification: