CHEM 3410 1st Edition Lecture 13Outline of CurrentI. Alcohol Reactivity: Alkoxide FormationII. Preparation of AlcoholsIII. Reduction of Aldehydes/ KetonesIV. Reductive of EstersV. Selective ReductionVI. Preparation of Alcohols from carbonyls reacted with Grignard ReagentsOutline of Last LectureVII. Table of Rules VIII. Alcohols IntroductionA. Primary, Secondary, Tertiary B. NamingC. Propertiesi. Hydrogen Bondingii. Rule of 8iii. Acidity/ Basicity Current LectureThese notes represent a detailed interpretation of the professor’s lecture. These notesare best used as a supplement to your own notes, not as a substitute.I. Alcohol Reactivity: Alkoxide FormationII. Preparation of AlcoholsIII. Reduction of Aldehydes and Ketones Example:III. Reduction of EstersV. Selective ReductionHere, you can see the difference in how the reagents will work on the compounds. NaBH4 is onlyefficient with carbonyls in family a (ketones, aldehydes), but LiAlH4 will reduce family A and family B carbonyls (like ester). You can selectively reduce based on this concept. V. Preparation of Alcohols from Carbonyls Reacted with Grignard
View Full Document
Unlocking...