Fall 2013- Chemistry 2311 Homework Problems- Chapter 11 (1) Give the IUPAC name for each of the following. (a) ClH2CCHClOHHCH3 (b) CH3CH3OHHHHO (c) HHOHClHC2H5 (d) OCH3OHHH (e)H3CCCH2CCH3HOOHHH (2) Draw the structure for each of the following. (a) (E)-But-2-en-1-ol (b) (S)-Butane-1,2,3-triol (c) (1R,2R)-Cyclopentane-1,2-diol (3) Complete each of the following reactions. (a)OH+NaHBr (b) OHHCHH3CH3CH3CH3C SClOOBase (c) OSOOCH3NaIAcetone (d) OHHPCl3 (e)OHSOCl2 (f) OHH2SO4, 140oC (g) HBr, refluxOH (h) OHSiClCH3CH3CCH3H3CCH3NC4H9C4H9C4H9C4H9+F-(4) Draw the structures for the following reaction sequence.H3CHClClNaNH2, liq.NH33 molesBrliq. NH3NaNH2, liq. NH3CH3(CH2)8CH2BrH2, Ni2BCOOHO(5) How would you carry out the following transformations. You may use any organic or inorganic reagents. (a) Cyclohexane to cyclohexyl methyl ether (b) Acetylene to 1-butanol (c) 2-butyne to meso-2,3-butanediol(6) Draw the mechanism for the following reactions. (a) OHHH2O, H+HOHHOH (b)
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