Reactions of Alcohols4. Hydration Reaction7. Dehydration of Alcohol to AlkeneSlide 48. Oxidation of Primary Alcohol to AldehydeSlide 69. Oxidation of Secondary Alcohol to KetoneSlide 8Slide 9Slide 10Slide 11Slide 1210. Oxidation of Aldehyde to Acid11. Ether synthesis from 2 alcoholsSlide 15Reactions of Alcohols•Reaction Summary:•4. Hydration: Alkene + water --> alcohol•7. Dehydration: Alcohol + heat --> alkene + H2•8. Oxidation: Pri. Alcohol + (O) --> aldehyde•9. Oxidation: Sec. Alcohol + (O) --> ketone•9B. Oxidation: Tert. Alcohol + (O) --> no reaction•10.Oxidation: Aldehyde + (O) --> Acid•11. Ether Synthesis: Alcohol + alcohol --> ether + HOH4. Hydration Reaction•Alkene + HOH --> alcohol•HOH molecule adds to carbons with double bond.CH2HCH3CCHCH3CHHCCMark's Rule+HOHHOHH3CCH CH3HOCCH3CHHHHOH7. Dehydration of Alcohol to Alkene•Subtraction: Remove -OH from alcohol carbon•Remove -H from a neighbor carbonH3CCHH3COHCCH3COHHHHHHOHCH2CHH3CReactions of Alcohols8. Oxidation of Primary Alcohol to Aldehyde•Subtraction: Remove -H from alcohol group•Remove -H from alcohol carbonHOHCH2H2CH3COHCH2CH3COHHH+(O)CHH2CH3COReactions of Alcohols9. Oxidation of Secondary Alcohol to Ketone•Subtraction: Remove -H from alcohol group•Remove -H from alcohol carbonHOH+(O)CH3CHH3COHCH3CH3COHHCH3CH3COReactions of AlcoholsReactions of AlcoholsReactions of AlcoholsReactions of AlcoholsReactions of AlcoholsCH3CHCHH3COHCH3+ (O)+ (O)H2CCHH2CH3COHCH3+ (O)H2CH3CSHH2CH3CSH+10. Oxidation of Aldehyde to Acid•Add oxygen from oxidizing agent•Insert O between H of carbon double oxygen+(O)CHH2CH3COCH2CH3COHCCH2H3COOH11. Ether synthesis from 2 alcohols•Subtraction: Remove -H from one alcohol group•Remove -OH from other alcohol carbon•Join two partsHOHH2CH3C OH+H2CCH3HOOH2CH3CH2CCH3Reactions of
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