Chem 153C 10/31/05glyoxylate and nitrogenaseGlyoxylate CycleFattyacyl-SCoAGlyoxylate CycleinBacteriaGlyoxylate Cycle in BacteriaGlucoseGlyoxylate Cycle in BacteriaAminoacidsAminoacidsNitrogenase StructureNitrogenase Fig. 26-67α2β2MoFe Protein α2β2λ2Fe ProteinReduced P clusterOxidized P clusterNitrogenase Fig. 26-67α2β2MoFe Protein α2β2λ2Fe ProteinFeMo CofactorFeMo Cofactor“…it is difficult to conceive of a process where by it[a single N atom] is inserted without some relation toN2 reduction. Indeed a monoatomic N is consistent withthe…. kinetic model that requires the resting state of theMoFe protein to be reduced by 3 e- before N2 can bind.Einsle et al (2002) Science 297, 1696-1700.Midterm #1 Stats:Avg = 42.7 + 17.6 High = 74Histogram012345678901020304050607080GradScore on
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