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APSU CHEM 3610 - Study Notes

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r2 c:\files\courses\3610\09final exam equations.docx Equations: nRTPV= RTPVzm= ( )nRTnbVvanP =−+22 dtdqC = nRCCVP=− γγffiiVPVP = PVUH+= VPwex∆−= VPw∆−= TnRw∆−= ∫= dTCwV −=ifVVnRTw ln ∆U = q + w H = U +PV A = U – TS G = H – TS ∆S (isothermal) = qrev/ T ∆S = Cv ln (Tf/Ti) (constant V) Constants: R = KmolJ⋅314.8, KmolLAtm⋅⋅08206.0, KmolLtorr⋅⋅36.62 Water: Cp(solid) = 2.06CgJ⋅, Cp(liquid) = 4.18CgJ⋅, Cp(gas) = 2.03CgJ⋅ Hf = 333gJ, Hv = 2260gJ PdVTdSdU−= VdPTdSdH+= PdVSdTdA−−= VdPSdTdG+−=r2 c:\files\courses\3610\09final exam equations.docx ()QRTmoleGG ln+∆=∆θ ( )−∆−=TTRmoleHKK1'1ln'lnθ mmVSdTdP∆∆= −∆−=121211lnTTRHPPsub −∆−=121211lnTTRHPPv ∆∆=−1212lnTTVHPPff ()()()AAAXRTll ln*+= µµ ( )2lnRTmoleHdTkdθ∆= kimT⋅⋅=∆ kXP⋅= cRT∆=Π *PXP⋅= [] []011AktA+= [][]ktAA−=0ln [][]0AktA+−=


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APSU CHEM 3610 - Study Notes

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