Dr. Peter Wipf Chemistry 0320 - Organic Chemistry 2 Recitation Set 2 Name________________________________ SID________________________________A. Provide products for the following reactions: a) O1. LDA, THF2. CH3CH2Br, HMPA b) O1. Me2CuLi, THF2. PhCH2Cl c) OONaOMe, MeOH d) OOMgBr+(excess)1. (CH3CH2)2O, 2. H3O+B. Propose a product and a suitable mechanism for the following reaction (describe electron movements with reaction arrows). Where does the label end up? If the starting material is 100% specifically labeled, what will be the degree of labeling of the product? CH3OH, heatH2SO4O18HOC. Propose a detailed synthetic approach from any precursors with 8 or less carbon atoms toward the following compound: OOCO2MeD. Provide suitable reagents for the following conversions: a) OHOOHOBr b) ClOO c) ClOOO O d)
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