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Quantities of Arsenic

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FLORIDA CENTERTABLE OF CONTENTSFlorida Registered Arsenical Pesticides from NPIR Database Search Conducted on April 29, 2003Florida Registered Arsenical Pesticides from NSPIRS Database Search That Were Not Identified on the NPIRS Database Search Conducted on April 29, 2003Annual Quantities of Phosphate Rock ExtractedLIST OF ABBREVIATIONS AND ACRONYMSLIST OF ABBREVIATIONS AND ACRONYMS \(con’d\)LIST OF ABBREVIATIONS AND ACRONYMS \(con’d\)II.1.a Input of Arsenic in CCA-Treated WoodFraction of As in Arsenic Trioxide by WeightFraction of As in MSMA by WeightConcentration of Arsenic in MSMA Concentrate SolutionFraction of As in DSMA by WeightConcentration of Arsenic in DSMA Concentrate SolutionInputSurface Area of Golf Courses in Florida= (Number of golf courses)(Net ave. surface area of golf courses)Surface ReservoirSurface Area of Golf Courses in Florida= (Number of golf courses)(Net surface area of golf courses)Geologic sources of arsenic evaluated in this section included those sources associated with phosphate rock mining (section II.3.a) and limestone mining (II.3.b).II.3.a Phosphate Rock MiningInput from the Florida Land Pebble Geologic ReservoirPhosphogypsum Produced Per Year (Cycled Arsenic)Phosphate Fertilizer OutputII.5.a Coal (Input)Mass of Coal Per Year = 2.73 x 107 short tons/yr= 2.48 x 1010 kg/yr (Note: 907 kg per short ton)II.5.b Petroleum (Input)II.6.a Fish and Shellfish (Input)II.7.b BiosolidsII.8.a RainwaterTotal Discharge of Water From River Entering State = 37,300 ft3/secTotal Discharge of Water From River Entering State = 80,900 ft3/secII.8.c Lakes and other Surface Waters (Surface Reservoir)II.8.d Groundwater (Accessible Reservoir)Flux of As(metric tons/yr)LimestoneFood SourcesShellfishBiosolids Imported from Other StatesWastewaterWastewaterBiosolidsLimestone in UseInsert A.1: Personal Communication with Robert Reese, USGSInsert A.2: Personal Communication with William Todd, UF Agricultural and Biological Engineering DepartmentInsert A.5: Personal Communication with Brian Birky of the FIPRTable A.6: Annual Quantities of Phosphate Rock Extracted(Personal Communication Gary Albarelli, FIPR, 2002)Granusol Zinc 36%Granusol Iron 50%EMJEOGranusol Iron 50%Granusol Manganese 35%Granular Ferric Sulfate 20%BLOQGranusol Copper/ZincMicronutrient FertilizerGranusol Manganese 35%GeorganiteM-8494Pel-LimeSul-Po MagNDCopper 25.2%Ammonium NitrateSee more info on As emissions from WTE facilities.Arsenic Compounds and Waste to Energy FacilitiesHillsborough County – McKay BayDade County – Miami Dade RRFWheelabrator North BrowardPinellas – Pinellas Co RRFWaste Water Treatment PlantAvg. Arsenic ConcentrationYear/Date of ReportingAltamonte Springs Regional Water Reclamation facility<0.01 mg/L08/21/01i Quantities of Arsenic Within the State of Florida Completed on June 30, 2003 Helena Solo-Gabriele, Ph.D., P.E. Donna-May Sakura-Lemessy, M.S. University of Miami, Coral Gables, FL Timothy Townsend, Ph.D., P.E. Brajesh Dubey Jenna Jambeck, M.S. University of Florida, Gainesville, FL State University System of Florida FLORIDA CENTER FOR SOLID AND HAZARDOUS WASTE MANAGEMENT 2207 NW 13 Street, Suite D Gainesville, FL 32609 Report #03-06ii This page left intentionally blank.iiiTABLE OF CONTENTS TABLE OF CONTENTS LIST OF FIGURES LIST OF TABLES LIST OF ABBREVIATIONS AND ACRONYMS UNITS OF MEASURE ABSTRACT iii iv iv vii ix xi CHAPTER I, MOTIVATION, OBJECTIVES, DISCLAIMER AND U.S. ARSENIC SOURCES I.1 Motivation and Objectives 2 I.2 Disclaimer 2 I.3 Summary of Arsenic Sources in the U.S. 3 CHAPTER II, SOURCES OF ARSENIC IN FLORIDA II.1 CCA-Treated Wood 11 II.2 Arsenical Pesticides Not Including CCA 15 II.3 Geologic Sources 28 II.4 Other Fertilizers (not from Phosphate Rock Mining) 36 II.5 Fuels 38 II.6 Food Sources 40 II.7 Wastes Generated Within the State 44 II.8 Hydrosphere (Rainfall, Rivers, and Soils) 48 II.9 Other 54 CHAPTER III, SUMMARY, CONCLUSIONS, AND RECOMMENDATIONS III.1 Summary 58 III.2 Conclusions and Recommendations 64 III.3 Acknowledgments 66 REFERENCES 67 APPENDIX A: SUPPLEMENTAL DATA AND DOCUMENTATION APPENDIX B: LIST OF TECHNICAL ADVISORY GROUP MEMBERS AND MEETING ATTENDEES 77 135ivLIST OF FIGURES Figure I.1 World and U.S. Production of Arsenic Figure I.2 Uses of Arsenic Within the USGS (from Edelstein 1994, 1995, & 1996; Reese 1997 to 2001; Loebenstein 1994) Figure II.1 Inputs, Outputs, Reservoirs, and Control Volumes for the State of Florida Figure II.2 Agricultural Use of MSMA and DSMA During 1992 and 1997 (Data from the National Center for Food and Agriculture Policy 2002) Figure II.3 Flow Chart of the Phosphate Fertilizer Production Process with Estimated Arsenic Concentrations Based Upon Mass Balance Considerations Figure III.1 Quantified Arsenic Input Fluxes for the State of Florida, 2000 Figure III.2 Arsenic Concentrations, ppm, for Components Evaluated in this Study Figure A.1 Dimensions of Typical Dipping Vats (provided by William Todd, UF Agricultural and Biological Engineering Department, personal communication, 2002) Figure A.2 Dipping Vat, 1925, Florida Library Photographic Collection (provided by William Todd, UF Agricultural and Biological Engineering Department, personal communication, 2002) LIST OF TABLES Table II.1 List of Keywords Used in NPIRS Database Search Table II.2 Number of Arsenical Pesticides Registered in Florida According to NPIRS (Products Separated By Those Used for Wood Preservation and Those Not Used for Wood Preservation) Table II.3 Sales Data for Non-CCA Arsenical Pesticides Sold in Florida Table II.4 Application Rates of Arsenical Herbicides on Florida Golf Courses (from Ma et al. 2002) Table II.5 Number of Applications of Arsenical Herbicides per Year for Florida Golf Courses (from Ma et al. 2002)vLIST OF TABLES (con’d) Table II.6 Arsenic Concentration in Phosphate (Data originally from FDACS. See table A.10 in appendix A) Table II.7 Fertilizers Containing Higher than 100 mg/kg Arsenic, Data Provided by FDACS Table III.1 Summary of Arsenic Inputs, Outputs, and Cycled Arsenic Sources in Florida Table III.2 Summary of Accessible and Geologic Reservoirs of Arsenic within Florida Table A.1 Arsenic Demand in the U.S. (from Edelstein 1994, 1995, & 1996; Reese 1997 to 2001; Loebenstein 1994) Table A.2


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